氢气具有来源丰富、可再生、能量密度高和燃烧清洁等优点,作为一种绿色、高效的新能源得到越来越多的关注。氢气的储运是氢能技术大规模应用的关键制约因素,储氢材料又是决定着储氢能力及其工业化应用的关键因素,因而研究合适的储氢材料成为发展氢能技术的重要环节。储氢方式可分为气态储氢、液态储氢和固态储氢。其中固态储氢更加安全高效,但是目前尚缺乏合适的可工业化生产的固体储氢材料。对固态储氢材料的研究进展进行了系统总结与展望。
Hydrogen energy has received more and more attention as a green and efficient new energy source,as well as the advantages of abundant sources,renewable,high energy density,and clean combustion.The storage and transportation of hydrogen is the key restricting factor for the large-scale application of hydrogen energy technology,and the hydrogen storage material is the key factor determining the hydrogen storage capacity and industrial application.Finding suitable hydrogen storage material has become an important link in the development of hydrogen energy technology.Hydrogen storage materials include three types:gas hydrogen storage,liquid hydrogen storage and solid hydrogen storage.Among of them,the solid-state hydrogen storage is relatively safe and efficient,but there is still a lack of suitable industrial hydrogen storage materials.The research progress of solid-state hydrogen storage materials was summarized and prospected.
[1] Shao Z H,Li Y,Liu C G,et al.Reversible interconversion between methanol-diamine and diamide for hydrogen storage based on manganese catalyzed(de)hydrogenation[J].Nature Communications,2020,11(1):1-7.
[2] Liu J,Zheng S Y,Zhang Z X,et al.Numerical study on the fast filling of on-bus gaseous hydrogen storage cylinder[J].International Journal of Hydrogen Energy,2020,45(15):9241-9251.
[3] Zhang Y H,Ji Y Q,Yuan Z M,et al.An investigation of gaseous hydrogen storage characterizations of Mg-Y-Ni-Cu alloys synthesized by melt spinning[J].RSC Advances,2018,8(51):28969-28977.
[4] Kim J B,Han G,Kwon Y K,et al.Thermal design of a hydrogen storage system using La(Ce)Ni5[J].International Journal of Hydrogen Energy,2020,45(15):8742-8749.
[5] Lokshin K A,Zhao Y S,He D W,et al.Structure and dynamics of hydrogen molecules in the novel clathrate hydrate by high pressure neutron diffraction[J].Physical Review Letters,2004,93(12):125503.
[6] Netskina O V,Tayban E S,Prosvirin I P,et al.Hydrogen storage systems based on solid-state NaBH4/Co composite:effect of catalyst precursor on hydrogen generation rate[J].Renewable Energy,2020,151,278-285.
[7] Zu L,Xu H,Zhang Q,et al.Design of filament-wound spherical pressure vessels based on non-geodesic trajectories[J].Composite Structures,2019,218,71-78.
[8] Agung T W,Takuya O,Chandra W P,et al.Liquid hydrogen,methylcyclohexane,and ammonia as potential hydrogen storage:comparison review[J].International Journal of Hydrogen Energy,2019,44(29):15026-15044.
[9] Wu Z,Zhu L Y,Yang F S,et al.First-principles insights into influencing mechanisms of metalloid B on Mg-based hydrides[J].Journal of Alloys and Compounds,2017,693,979-988.
[10] Tetsuo U,Yan J M,Zhang X B,et al.Co-SiO2 nanosphere-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage[J].Journal of Power Sources,2010,195,8209-8214.
[11] Abdelkrim A,Saadia N,Nabil B,et al.Metal-inorganic-organic matrices as efficient sorbents for hydrogen storage[J].Chemsus Chem,2015,8:800-803.
[12] Ma Z W,Zou J X,Darvaish K,et al.Preparation and hydrogen storage properties of MgH2-trimesic acid-TM MOF (TM=Co,Fe) composites[J].Journal of Materials Science & Technology,2019,35(10):2132-2143.
[13] Jang H S,Mun J,Hong W G,et al.The performance of green carbon as a backbone for hydrogen storage materials[J].International Journal of Hydrogen Energy,2020,45(17):10516-10522.
[14] 杨小平,田景文.固体储氢材料的研究进展[J].化工管理,2015(16):95-97.
[15] Ting V P,Ramirez-Cuesta A J,Bimbo N,et al.Direct evidence for solid-like hydrogen in a nanoporous carbon hydrogen storage material at supercritical temperatures[J].ACS Nano,2015,9(8):8249-54.
[16] Shang H W,Li Y Q,Zhang Y H,et al.Influence of adding nano-graphite powders on the microstructure and gas hydrogen storage properties of ball-milled Mg90Al10 alloys[J].Carbon,2019,149,93-104.
[17] James L W,Alexander A B,Matthew A M,et al.The inside-outs of metal hydride dehydrogenation:imaging the phase evolution of the Li-N-H hydrogen storage system[J].Advanced Materials Interfaces,2020,7(7):1901905.
[18] Atef C,Slimane M,Cherif B,et al.Heat and mass transfer during the storage of hydrogen in LaNi5-based metal hydride:2D simulation results for a large scale,multi-pipes fixed-bed reactor[J].International Journal of Heat and Mass Transfer,2020,147,118939.
[19] Ika D W,Roman D,Suwarno,et al.Hydrides of Laves type Ti-Zr alloys with enhanced H storage capacity as advanced metal hydride battery anodes[J].Journal of Alloys and Compounds,2020,828,154354.
[20] Ding Z,Li H,Shaw L.New insights into the solid-state hydrogen storage of nanostructured LiBH4-MgH2 system[J].Chemical Engineering Journal,2020,385,123856.
[21] Nurten B D,Mustafa A.Synthesis of La2MgNi9 hydrogen storage alloy in molten salt[J].International Journal of Hydrogen Energy,2020,45(15):8750-8756.
[22] Wang W F,Qin R Y,Wu R X,et al.A promising anode candidate for rechargeable nickel metal hydride power battery:an A5B19-type La-Sm-Nd-Mg-Ni-Al-based hydrogen storage alloy[J].Journal of Power Sources,2020,465,228236.
[23] Lu Y,JingL,Fei L,et al.Significantly improved cycling stability for electrochemical hydrogen storage in Ti1.4V0.6Ni alloy with TiN[J].Materials Research Bulletin,2019,118,55-58.
[24] Xia G,Meng Q,Guo Z,et al.Nanoconfinement significantly improves the thermodynamics and kinetics of co-infiltrated 2LiBH4-LiAlH4 composites:stable reversibility of hydrogen absorption/resorption[J].Acta Materialia,2013,61(18):6882-6893.
[25] Dixon D A,Gutowski M.Thermodynamic properties of molecular borane amines and the [BH-4][NH+4] salt for chemical hydrogen storage systems from ab initio electronic structure theory[J].Journal of Physical Chemistry A,2005,109(23):5129-5135.
[26] 秦董礼,赵晓宇,张轲,等.组成对Li-Mg-N-H系统储氢性能的影响[J].稀有金属材料与工程,2015,44(2):355-359.
[27] Petit J F,Miele P,Demirci U B.Ammonia borane H3NBH3 for solid-state chemical hydrogen storage:different samples with different thermal behaviors[J].International Journal of Hydrogen Energy,2016,41(34):15462-15470.
[28] ]Wang Y Q,Lan Z Q,Huang A T,et al.Study on catalytic effect and mechanism of MOF(MOF=ZIF-8,ZIF-67,MOF-74) on hydrogen storage properties of magnesium[J].International Journal of Hydrogen Energy,2019,44(54):28863-28873.
[29] Sridhar P,Niket S K.A critical analysis of transport models for refueling of MOF-5 based hydrogen adsorption system[J].Journal of Industrial and Engineering Chemistry,2020,85:170-180.
[30] 辛金鹏,吴昱廷,李松,等.具有边缘传递网的稀土MOFs(RE-shp-MOF-1,RE-alb-MOF-1)储氢性能模拟研究[J].四川大学学报(自然科学版),2019,56(4):727-734.
[31] Kaye S S,Dailly A,Yaghi O M,et al.Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)[J].Journal of the American Chemical Society,2007,129(46):14176.
[32] Sonwabo E B,Henrietta W L,Robert M,et al.Compaction of a zirconium metal-organic framework (UiO-66) for high density hydrogen storage applications[J].Journal of Materials Chemistry A,2018,6:23569-23577.
[33] 臧小亚,梁德青,吴能友.碳纳米管和碳纳米管-四氢呋喃水合物的储氢特性[J].高等学校化学学报,2012,33(3):580-585.
[34] Mao W L,Mao H K,Goncharov A F,et al.Hydrogen clusters in clathrate hydrate[J].Science,2002,297,2247.
[35] 陈俊,陈秋雄,陈运文,等.水合物储能技术研究现状[J].储能科学与技术,2015,4(2):131-140.
[36] Yu C,Fan S,Lang X,et al.Hydrogen and chemical energy storage in gas hydrate at mild conditions[J].International Journal of Hydrogen Energy,2020,45(29):14915-14921.
基金资助
国家自然科学基金(51103012)
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